Automatic dishwashing, particularly in domestic appliances, is an art very different from fabric laundering. Domestic fabric laundering is normally done in purpose-built machines having a tumbling action. These are very different from spray-action domestic automatic dishwashing appliances. The spray action in the latter tends to cause foam. Foam can easily overflow the low sills of domestic dishwashers and slow down the spray action, which in turn reduces the cleaning action. Thus, in the distinct field of domestic machine dishwashing, the use of common foam-producing laundry detergent surfactants is normally restricted. These aspects are but a brief illustration of the unique formulation constraints in the domestic dishwashing field.
Automatic dishwashing with bleaching chemicals is different from fabric bleaching. In automatic dishwashing, use of bleaching chemicals involves promotion of soil removal from dishes, though soil bleaching may also occur. Additionally, soil antiredeposition and anti-spotting effects from bleaching chemicals are desirable. Some bleaching chemicals (such as a hydrogen peroxide source, alone or together with tetraacetylethylenediamine, a.k.a. "TAED") can, in certain circumstances, be helpful for cleaning dishware
On account of the foregoing technical constraints as well as consumer needs and demands, automatic dishwashing detergent (ADD) compositions are undergoing continual change and improvement. Moreover environmental factors such as the restriction of phosphate, the desirability of providing ever-better cleaning results with less product, providing less thermal energy, and less water to assist the washing process, have all driven the need for improved ADD compositions.
However, one area of ADD technology which has not received sufficient focus is in the area of perfumes and fragrances which deliver a pleasurable scent to the cleaned dishware and flatware and also serve to signal that the dishes are clean. Surprisingly the .beta.-ketoester pro-fragrances of the present invention are stable to the ingredients which comprise ADD compositions and are readily released both during the wash and rinse cycles as well as during the drying cycle. When ADD compositions which comprise the .beta.-ketoesters of the present invention are used the consumer experiences a "fresh" and "cleaned" smell once the dishwasher is opened. The .beta.-ketoester pro-fragrances are adaptable to the needs of the formulator, for example, the pro-fragrances can be designed to be releasable upon extended contact with water, or they can be heat labile. In addition, the formulator may wish to provide a fragrance admixture or "accord" wherein some fragrances are released by contact with water while others are activated by heat. This allows for the delivery of fragrance raw material alcohols via pro-fragrances even when "energy-minders", for example, nil or low heat dryers, are used by the consumer.
Accordingly, there remains a need in the art for a fragrance delivery system wherein fragrance raw material alcohols are delivered to flatware and tableware by way of an ADD composition which provides the tableware and flatware with a "fresh" or "clean" scent after washing.